📚 Year 12 Edexcel Science: Quick Reference Handbook of Formulas and Theorems | Year 12 爱德思科学:公式定理速查手册
This handbook compiles the key formulas, theorems, and essential concepts from Year 12 (AS-level) Physics, Chemistry, and Biology for the Edexcel specification. Use it as a rapid revision tool to strengthen your understanding and boost exam confidence.
本手册汇编了 Year 12(AS 阶段)爱德思物理、化学和生物课程中的核心公式、定理和重要概念,可用作快速复习工具,帮助你巩固理解并提升应试信心。
1. Kinematics and Dynamics | 运动学与动力学
For objects moving with constant acceleration, the SUVAT equations link displacement (s), initial velocity (u), final velocity (v), acceleration (a), and time (t).
对于匀加速直线运动,以下 SUVAT 方程关联位移 s、初速度 u、末速度 v、加速度 a 和时间 t。
| Equation | Missing variable |
| v = u + at | s |
| s = ½(u + v)t | a |
| s = ut + ½at² | v |
| v² = u² + 2as | t |
Newton’s second law states that the net force acting on a body is equal to the rate of change of its momentum, often simplified to F = ma for constant mass. Weight is W = mg, with g = 9.81 m s⁻² on Earth.
牛顿第二定律指出,物体所受合力等于其动量的变化率,常简化为 F = ma(质量恒定)。重量 W = mg,地球表面的 g = 9.81 m s⁻²。
Momentum p is defined as mass × velocity: p = mv. Impulse is the change in momentum: FΔt = Δp. The principle of conservation of momentum (total momentum before = total momentum after) is vital for collision and explosion problems.
动量 p 定义为质量 × 速度,即 p = mv。冲量引起动量的改变:FΔt = Δp。动量守恒定律(碰撞前后总动量不变)是处理碰撞和爆炸问题的关键。
Work done by a constant force: W = Fd cos θ, where θ is the angle between force and displacement. Kinetic energy KE = ½mv², gravitational potential energy GPE = mgΔh. Power is the rate of doing work: P = W/t = Fv.
恒力做功:W = Fd cos θ,θ 为力与位移间的夹角。动能 KE = ½mv²,重力势能 GPE = mgΔh。功率为做功的速率:P = W/t = Fv。
2. Materials, Waves and Optics | 材料、波与光学
Stress = F / A (unit: Pa), strain = ΔL / L₀ (no unit), and the Young modulus E = stress / strain, representing stiffness of a material within elastic limit.
应力 = F / A(单位 Pa),应变 = ΔL / L₀(无单位),杨氏模量 E = 应力 / 应变,表示材料在弹性限度内的刚度。
All waves satisfy the wave equation: v = f λ, where v is speed, f is frequency and λ is wavelength. Wave intensity I is proportional to amplitude².
所有波都满足波动方程:v = f λ,其中 v 为波速,f 为频率,λ 为波长。波的强度 I 与振幅的平方成正比。
Refractive index n = c / v (where c = 3.00 × 10⁸ m s⁻¹). Snell’s law: n₁ sin θ₁ = n₂ sin θ₂. For total internal reflection, the critical angle c satisfies sin c = n₂ / n₁ (valid when n₁ > n₂).
折射率 n = c / v(c = 3.00 × 10⁸ m s⁻¹)。斯涅耳定律:n₁ sin θ₁ = n₂ sin θ₂。发生全内反射时,临界角 c 满足 sin c = n₂ / n₁(需 n₁ > n₂)。
The thin lens formula: 1/f = 1/u + 1/v, where f is focal length, u is object distance, v is image distance (real positive). Linear magnification m = v / u.
薄透镜公式:1/f = 1/u + 1/v,f 为焦距,u 为物距,v 为像距(实像取正值)。线放大率 m = v / u。
3. Electricity and Circuits | 电学与电路
Ohm’s law: V = IR, defining resistance R in ohms (Ω). Resistivity ρ relates resistance to geometry: R = ρL / A, where L is length and A is cross-sectional area.
欧姆定律:V = IR,定义电阻 R,单位欧姆(Ω)。电阻率 ρ 将电阻与材料几何尺寸关联:R = ρL / A,L 为长度,A 为横截面积。
Electrical power can be expressed as P = IV = I²R = V² / R. Energy transferred E = Pt = IVt.
电功率表示为 P = IV = I²R = V² / R。传递的电能 E = Pt = IVt。
For resistors in series: Rtotal = R₁ + R₂ + … ; for parallel: 1/Rtotal = 1/R₁ + 1/R₂. Capacitors in parallel: Ctotal = C₁ + C₂; in series: 1/Ctotal = 1/C₁ + 1/C₂.
电阻串联:R总 = R₁ + R₂ + …;并联:1/R总 = 1/R₁ + 1/R₂。电容并联:C总 = C₁ + C₂;串联:1/C总 = 1/C₁ + 1/C₂。
A real cell has emf ε and internal resistance r. The terminal pd V = ε – Ir. The potential divider formula: Vout = Vin × (R₂ / (R₁ + R₂)).
实际电源有电动势 ε 和内阻 r。路端电压 V = ε – Ir。电位器分压公式:Vout = Vin × (R₂ / (R₁ + R₂))。
4. Quantum Phenomena and Particle Physics | 量子现象与粒子物理
Photon energy: E = hf = hc / λ, where Planck constant h = 6.63 × 10⁻³⁴ J s. The electronvolt: 1 eV = 1.60 × 10⁻¹⁹ J.
光子能量:E = hf = hc / λ,普朗克常量 h = 6.63 × 10⁻³⁴ J s。电子伏特:1 eV = 1.60 × 10⁻¹⁹ J。
Einstein’s photoelectric equation: hf = φ + ½mv²max, where φ is the work function of the metal. The threshold frequency f₀ is given by φ = hf₀. Photocurrent increases with intensity, while maximum kinetic energy depends only on frequency.
爱因斯坦光电方程:hf = φ + ½mv²max,φ 为金属的逸出功。阈频率 f₀ 满足 φ = hf₀。光电流随光强增大,而最大动能只取决于频率。
De Broglie wavelength of a particle: λ = h / p, where p = mv is momentum. This explains electron diffraction.
实物粒子的德布罗意波长:λ = h / p,p = mv 为动量,该式可解释电子衍射现象。
In particle interactions, charge, baryon number and lepton number are conserved. Proton = uud, neutron = udd. The weak interaction can change quark flavour.
在粒子相互作用中,电荷、重子数和轻子数守恒。质子由 uud 夸克组成,中子由 udd 组成。弱相互作用可以改变夸克味。
5. Quantitative Chemistry and the Mole | 定量化学与摩尔
The mole links mass, volume, and number of particles. Amount n = m / M, where m is mass and M is molar mass (g mol⁻¹). For gases at RTP (room temperature and pressure, Edexcel assumes 24.0 dm³ mol⁻¹): n = V (in dm³) / 24.0.
摩尔连接质量、体积和粒子数。物质的量 n = m / M,m 为质量,M 为摩尔质量(g mol⁻¹)。在室温常压(RTP,爱德思取 24.0 dm³ mol⁻¹)下,气体 n = V (dm³) / 24.0。
Concentration c = n / V (units mol dm⁻³), often obtained by titration. Standard solutions require precise mass or volume measurements.
浓度 c = n / V(单位 mol dm⁻³),常通过滴定法获得。配制标准溶液需精确称量或体积量取。
Ideal gas equation: pV = nRT, where p is pressure (Pa), V is volume (m³), T is absolute temperature (K), and R = 8.31 J K⁻¹ mol⁻¹. (Note: units must be consistent.)
理想气体方程:pV = nRT,p 为压强(Pa),V 为体积(m³),T 为绝对温度(K),R = 8.31 J K⁻¹ mol⁻¹。使用时单位必须一致。
Percentage yield = (actual yield / theoretical yield) × 100%. Atom economy = (molar mass of desired product / total molar mass of all reactants) × 100%. These measure reaction efficiency.
产率百分比 =(实际产量 / 理论产量)× 100%。原子经济性 =(目标产物的摩尔质量 / 所有反应物摩尔质量之和)× 100%,两者共同衡量反应效率。
Empirical formula gives simplest whole-number ratio of atoms; molecular formula = n × empirical formula, where n = relative molecular mass / empirical formula mass.
实验式给出原子最简整数比;分子式 = n × 实验式,其中 n = 相对分子质量 / 实验式质量。
6. Energetics and Bond Enthalpies | 能量学与键焓
Heat transferred to a solution: q = mcΔT, where m is mass, c is specific heat capacity (often 4.18 J g⁻¹ K⁻¹ for water), and ΔT is temperature change. Enthalpy change ΔH = -q / n (negative for exothermic, positive for endothermic, assuming heat absorbed by surroundings).
溶液吸收或释放的热量:q = mcΔT,m 为质量,c 为比热容(水常取 4.18 J g⁻¹ K⁻¹),ΔT 为温度变化。焓变 ΔH = -q / n(放热为负,吸热为正,假设热量由环境吸收)。
Hess’s law states that the total enthalpy change for a reaction is independent of the route. Using standard formation enthalpies: ΔH°reaction = Σ ΔH°f(products) – Σ ΔH°f(reactants).
赫斯定律指出,反应的总焓变与途径无关。利用标准生成焓计算:ΔH°反应 = Σ ΔH°f(产物) – Σ ΔH°f(反应物)。
Bond enthalpy approximation: ΔH ≈ Σ (bond enthalpies of bonds broken) – Σ (bond enthalpies of bonds formed). This average method works best for gaseous reactions.
键焓近似计算:ΔH ≈ Σ(断裂键的键焓)- Σ(形成键的键焓)。这种平均值方法最适合气态反应。
7. Introduction to Organic Chemistry | 有机化学入门
Functional groups define homologous series: alkanes (C-C single bonds), alkenes (C=C double bond), halogenoalkanes (-X), alcohols (-OH), aldehydes (-CHO), ketones (C=O between carbons), carboxylic acids (-COOH), esters (-COO-), amines (-NH₂), amides (-CONH₂), nitriles (-C≡N).
官能团定义同系物:烷烃(C-C 单键)、烯烃(C=C 双键)、卤代烷(-X)、醇(-OH)、醛(-CHO)、酮(碳间 C=O)、羧酸(-COOH)、酯(-COO-)、胺(-NH₂)、酰胺(-CONH₂)、腈(-C≡N)。
Reaction types to recognise: addition (alkene → alkane/ alcohol), electrophilic addition (alkenes with HX or Br₂), free-radical substitution (alkanes with halogens under UV), oxidation (alcohol → aldehyde → carboxylic acid), elimination (alcohol → alkene), condensation (esterification, amide formation), hydrolysis.
应识别的反应类型:加成(烯→烷/醇),亲电加成(烯烃与 HX 或 Br₂),自由基取代(烷烃与卤素在紫外线下),氧化(醇→醛→羧酸),消除(醇→烯),缩合(酯化、酰胺化),水解。
Structural isomers share the same molecular formula but differ in carbon skeleton or functional group. Stereoisomers (E/Z) arise from restricted rotation around double bonds or ring structures.
结构异构体分子式相同,但碳链或官能团连接方式不同。立体异构体(E/Z)由双键或环状结构限制旋转而产生。
8. Biological Molecules | 生物分子
Monomers join by condensation reactions (releasing water) and polymers are broken by hydrolysis. Key monosaccharides: α-glucose and β-glucose (C₆H₁₂O₆). Disaccharides include maltose (glucose + glucose, α-1,4 glycosidic bond), sucrose (glucose + fructose), lactose (glucose + galactose).
单体通过缩合反应连接(脱去水),聚合物通过水解断裂。关键单糖:α- 和 β- 葡萄糖(C₆H₁₂O₆)。二糖包含麦芽糖(葡萄糖+葡萄糖,α-1,4 糖苷键)、蔗糖(葡萄糖+果糖)、乳糖(葡萄糖+半乳糖)。
Polysaccharides: starch (amylose and amylopectin, plant energy store), glycogen (animal storage, highly branched), cellulose (β-1,4 glycosidic bonds, plant cell walls – long straight chains with hydrogen bonds).
多糖:淀粉(直链淀粉与支链淀粉,植物储能)、糖原(动物储能,高度支化)、纤维素(β-1,4 糖苷键,植物细胞壁,长直链间形成氢键)。
Triglycerides consist of one glycerol molecule ester-linked to three fatty acid chains. Phospholipids have two fatty acids and a phosphate group, forming the bilayer basis of cell membranes.
甘油三酯由一个甘油分子与三条脂肪酸链通过酯键连接而成。磷脂含有两条脂肪酸和一个磷酸基团,构成细胞膜脂双层的基础。
Proteins are polymers of amino acids. General amino acid structure: H₂N–CHR–COOH. Peptide bonds form between amino acids. Primary structure = sequence; secondary = α-helices / β-pleated sheets (H-bonds); tertiary = 3D folding (ionic, disulfide, hydrophobic interactions, H-bonds); quaternary = multiple polypeptide chains.
蛋白质是氨基酸的聚合物。氨基酸通式:H₂N–CHR–COOH。肽键在氨基酸间形成。一级结构为序列;二级结构为 α-螺旋/β-折叠(氢键维系);三级结构为三维折叠(离子键、二硫键、疏水作用、氢键等);四级结构为多条多肽链的组合。
Nucleotides consist of a phosphate group, a pentose sugar (ribose/deoxyribose), and a nitrogenous base. DNA double helix has complementary base pairing A-T and G-C, held by hydrogen bonds. RNA contains uracil instead of thymine and is single-stranded.
核苷酸由磷酸基团、五碳糖(核糖/脱氧核糖)和含氮碱基组成。DNA 双螺旋中 A 与 T、G 与 C 通过氢键互补配对。RNA 含尿嘧啶代替胸腺嘧啶,通常为单链。
9. Cell Membranes and Transport | 细胞膜与物质运输
The fluid mosaic model describes membranes as a phospholipid bilayer with embedded proteins (channel and carrier), cholesterol (regulating fluidity), and glycoproteins/glycolipids (cell recognition).
流动镶嵌模型将膜描绘为磷脂双分子层,其中散布着蛋白质(通道蛋白和载体蛋白)、胆固醇(调节流动性),以及糖蛋白/糖脂(细胞识别)。
Diffusion is net movement of particles from high to low concentration, described by Fick’s law: rate of diffusion ∝ (surface area × concentration difference) / thickness of exchange surface.
扩散是粒子从高浓度区间向低浓度区的净移动,符合菲克定律:扩散速率 ∝ (表面积 × 浓度差)/ 交换面厚度。
Osmosis is the diffusion of water through a partially permeable membrane from a region of higher water potential (ψ) to lower water potential. Pure water ψ = 0; solutions have negative ψ. ψ = ψs (solute potential) + ψp (pressure potential).
渗透是水通过部分通透膜的扩散,从高水势(ψ)移向低水势。纯水 ψ = 0;溶液水势为负值。水势 ψ = ψs(溶质势)+ ψp(压力势)。
Active transport uses ATP to move substances against their concentration gradient via specific carrier proteins. Co-transport couples the movement of one substance (e.g. glucose) with the downhill movement of Na⁺ ions.
主动运输利用 ATP,通过特定的载体蛋白将物质逆浓度梯度转运。协同转运将一种物质的移动(如葡萄糖)与 Na⁺ 离子的顺梯度移动相偶联。
10. Enzymes and Metabolism | 酶与代谢
Enzymes are biological catalysts that lower activation energy, speeding up reactions without being used up. The induced-fit model states that the active site changes shape slightly to bind substrate, forming enzyme-substrate complexes.
酶是生物催化剂,能降低活化能,从而加快反应且自身不被消耗。诱导契合模型认为,酶的活性中心发生轻微形变以结合底物,形成酶-底物复合体。
Rate of enzyme-catalysed reactions increases with temperature up to an optimum; beyond this, denaturation occurs as hydrogen bonds break. pH also affects rate by altering ionic interactions at the active site.
酶促反应速率随温度升高而增加直至最适温度;超过最适温度则酶变性,氢键断裂。pH 值通过改变活性中心的离子相互作用来影响反应速率。
As substrate concentration increases, rate rises until all active sites are saturated, reaching Vmax. The Michaelis-Menten equation models this, though AS focuses on qualitative understanding of Vmax and competitive/non-competitive inhibition.
随底物浓度增加,反应速率升高,直至所有活性位点饱和,达到最大速率 Vmax。米氏方程对此进行了模型化,但 AS 阶段主要定性理解 Vmax 和竞争性/非竞争性抑制的作用。
Competitive inhibitors resemble the substrate and bind to the active site; their effect can be overcome by increasing substrate concentration. Non-competitive inhibitors bind elsewhere, altering enzyme shape and reducing Vmax.
竞争性抑制剂与底物结构相似
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