📚 Alcohols, Esters and Carboxylic Acids | 醇、酯和羧酸
Alcohols, esters and carboxylic acids are three closely linked oxygen-containing organic families. Their interconversions, especially esterification and oxidation, form a central part of Cambridge A-Level Chemistry.
醇、酯和羧酸是三类密切相关的含氧有机物家族。它们的相互转化——尤其是酯化和氧化——是剑桥 A-Level 化学的核心内容。
1. Functional Groups and Classification | 官能团与分类
Alcohols contain the hydroxyl group –OH attached to a saturated carbon atom. Carboxylic acids contain the carboxyl group –COOH, while esters contain the –COO– linkage.
醇含有连接在饱和碳原子上的羟基 –OH;羧酸含有羧基 –COOH;酯则含有 –COO– 键。
Alcohols are classified as primary, secondary or tertiary according to the number of carbon atoms bonded to the carbon bearing the –OH group.
根据与羟基所连碳原子相连的碳原子数目,醇可分为伯醇、仲醇和叔醇。
| Type | Structure | Example |
|---|---|---|
| Primary (1°) | RCH₂OH | Ethanol CH₃CH₂OH |
| Secondary (2°) | R₂CHOH | Propan-2-ol CH₃CH(OH)CH₃ |
| Tertiary (3°) | R₃COH | 2-Methylpropan-2-ol (CH₃)₃COH |
2. Naming Alcohols | 醇的命名
For IUPAC naming, choose
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